Azobisisobutyronitrile → Styrenesulfonic Acid Allylhexafluoro-Isopropanol

HRID 254138

反応式

[CH:1]([S:9]([O-:12])(=[O:11])=[O:10])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[Na+].N(C(C)(C)C#N)=NC(C)(C)C#N.[CH2:26]([C:29]([OH:38])([C:34]([F:37])([F:36])[F:35])[C:30]([F:33])([F:32])[F:31])[CH:27]=[CH2:28]>CS(C)=O>[CH:1]([S:9]([OH:12])(=[O:10])=[O:11])=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[CH2:26]([C:29]([OH:38])([C:30]([F:32])([F:33])[F:31])[C:34]([F:35])([F:36])[F:37])[CH:27]=[CH2:28]

参加物

実験手順

19 g of sodium styrenesulfonate (SSNa) (available from Sigma-Aldrich Corp.) and 1 g of 2-Allylhexafluoro-isopropanol are fully dissolved in 0.24 L of dimethylsulfoxide (DMSO) with heating. Then, 0.1 g of azobisisobutyronitrile (AIBN) is added dropwise to the DMSO solution. The monomers are polymerized for 24 hours or more. The polymerization is carried out varying the content of the allylhexafluoro-isopropanol (2, 5, 10, and 20 wt %).

後処理

temperaturewith heating
customThe monomers are polymerized for 24 hours or more

出典と根拠

ORDレコード: ord-ed02a1056370470d86ee721b3d2d6bbb
出典データセット: uspto-grants-2011_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07875208B2

反応式

参加物

反応物 3

生成物 1

試薬・触媒・溶媒 1

実験手順

後処理

出典と根拠

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