Sodium Hydroxide → Beta-D-Glucose 6-phosphate

HRID 256704ノート

反応式

HRID 256704 の反応式
[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C@@H:10]([OH:13])[CH:11]=[O:12])([O-:4])([O-:3])=[O:2].[Ba+2].[OH-].[Na+].[BH4-].[Na+]>O>[CH2:6]([O:5][P:1]([OH:3])([OH:4])=[O:2])[C@H:7]1[O:16][C@@H:11]([OH:12])[C@H:10]([OH:13])[C@@H:9]([OH:14])[C@@H:8]1[OH:15]

参加物

5

反応物 3

HCID 14798Sodium HydroxideHCID 111125Barium glucose 6-phosphateHCID 4311764Sodium borohydride

生成物 1

HCID 439427Beta-D-Glucose 6-phosphate

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
45 °C

実験手順

To 10 ml of the aminated gel obtained in Preparation Example 2 were added, first 10 ml of water, next 1 g of barium glucose-6-phosphate, to which 0.5 ml of 2M NaOH was further added and the mixture was maintained at 45° C. for 1 hour. After 0.1 g of NaBH4 was added thereto, the mixture was allowed to stand at room temperature for 24 hours. After the reaction was completed, the gel was filtered off from the reaction mixture and washed with water to give a cellulose gel with immobilized glucose-6-phosphate. The amount of the introduced anionic functional group derived from the immobilized glucose-6-phosphate was 10 μmol to 1 ml of the adsorbent.

後処理

  1. additionwere added
  2. filtrationthe gel was filtered off from the reaction mixture
  3. washwashed with water

出典と根拠

ORDレコード
ord-bed67b7f3eff4616bf94a00e5dfb7fe8
出典データセット
uspto-grants-1993_11
特許番号
US05258503

反応ノート

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