Cyclohexanone → Prop-2-enenitrile--ethenylbenzene (1/1)

HRID 256788

反応式

HRID 256788 の反応式
[CH:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][N:2]=1.C1(=O)CCCCC1>CN1CCCC1=O.[Cu]I>[CH2:9]=[CH:10][C:1]#[N:2].[CH2:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

参加物

5

反応物 2

HCID 7967CyclohexanoneHCID 8405Isoquinoline

生成物 1

HCID 62696Prop-2-enenitrile--ethenylbenzene (1/1)収率 10%

試薬・触媒・溶媒 2

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)触媒HCID 13387N-methyl-2-pyrrolidone溶媒

実験手順

A solution of 2.0 g. CuI, 1.4 g. isoquinoline (1:1 ratio), 50.0 g. N-methylpyrrolidone solvent, 46.6 g. cyclohexanone and 0.20 g. Lustran SAN 31-1,000 (10% on CuI) was prepared. The resulting coating solution was coated on 7 mil raw PET with number 10 Meyer rod and dried three minutes at 240° F. The coating had very good uniformity and clarity and was gold and blue iridescent and lustrous. The resistivity measured 13-20×107 Ω/sq. The solution after time showed some precipitation, which crystals were redissolved upon reheating.

後処理

  1. customdried three minutes at 240° F
  2. customsome precipitation, which crystals
  3. dissolutionwere redissolved

出典と根拠

ORDレコード
ord-3110b0bfc3814e4280160de68cfb5d7b
出典データセット
uspto-grants-1993_11
特許番号
US05259992

関連ノート

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