Propionitrile → 2-Nonenenitrile, 2,3-dimethyl-
反応式
[CH3:1][C:2](=O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:10](#[N:13])[CH2:11][CH3:12].[O-2].[Ca+2].[OH-].C[N+](C)(C)C>O>[CH3:12][C:11](=[C:2]([CH3:1])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[C:10]#[N:13]参加物
6
反応条件
- 温度
- 103 °C
実験手順
Into a 100 ml. flask, equipped with a magnetic stirrer, thermometer, condensor, and static nitrogen head, was placed 13.6 g. of 2-octanone, 11 g. of propionitrile, 61 g. of calcium oxide and 0.3 g. of 25% tetramethyl ammonium hydroxide in water. The mixture was held at reflux (103° C.) for 16 hours at which time gas chromatographic analysis showed 7% product nitrile relative to starting ketone.
後処理
- customflask, equipped with a magnetic stirrer
出典と根拠
- ORDレコード
- ord-526caeda957f4c6ca162f39a48ff715a
- 出典データセット
- uspto-grants-1979_05
- 特許番号
- US04156690
反応ノート
読み込み中…