Phenylphosphonic Acid → Adipic Acid

HRID 267704

反応式

HRID 267704 の反応式
[C:1]([O-:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O-:8])=[O:7].[NH3+]CCCCCC[NH3+].C1(P(=O)(O)O)C=CC=CC=1.NCCCCCCN>O>[C:1]([OH:10])(=[O:9])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([OH:8])=[O:7]

参加物

5

反応物 3

HCID 15295Phenylphosphonic Acid2 回HCID 16402Hexamethylenediamine2 回HCID 273586-Azaniumylhexylazanium;hexanedioate

生成物 1

HCID 196Adipic Acid

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture of 100 parts of hexamethylene diammonium adipate, 0.65 part of phenylphosphonic acid, 0.48 part of hexamethylenediamine, 0.65 part of N:N'-bis(3-aminopropyl)piperazine, 0.46 part of adipic acid and 65.0 parts of water is polymerised using the conditions described in Example 1. The resulting polymer is then converted into fibres by known methods. The dye uptake of these fibres from dyebaths containing Solway Blue BN at pH's of 4.0, 7.0 and 9.0 are 8.4%, 4.7% and 1.5% respectively, compared with 4.2%, 0.6% and 0.1% for fibres prepared as described in this Example except that the phenylphosphonic acid and hexamethylenediamine were omitted from the mixture.

後処理

  1. additionThe dye uptake of these fibres from dyebaths containing Solway Blue BN at pH's of 4.0, 7.0 and 9.0
  2. customprepared

出典と根拠

ORDレコード
ord-e71604194418479ea58f3e9332e592d0
出典データセット
uspto-grants-1976_03
特許番号
US03944518

関連ノート

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