Triethyl Citrate → 1,2,3-Triethyl 1,2,3-propanetricarboxylate
反応式
[C:1]([O:17][CH2:18][CH3:19])(=[O:16])[CH2:2][C:3]([CH2:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])([C:5]([O:7][CH2:8][CH3:9])=[O:6])O.O1CCCC1.[H][H]>C(O)C>[CH2:2]([C:1]([O:17][CH2:18][CH3:19])=[O:16])[CH:3]([C:5]([O:7][CH2:8][CH3:9])=[O:6])[CH2:10][C:11]([O:13][CH2:14][CH3:15])=[O:12]参加物
5
実験手順
400 ml of triethyl citrate were hydrogenated at 175° C. and 10 bar together with 1100 ml of tetrahydrofuran and 60 g of catalyst G (4-mm tablets) until the take-up of hydrogen had ceased. The reaction product was freed from ethanol and distilled under reduced pressure, giving 193 g (45%) of triethyl propane-1,2,3-tricarboxylate.
後処理
- customwere hydrogenated at 175° C.
- distillationdistilled under reduced pressure
出典と根拠
- ORDレコード
- ord-fdfd6c8e013d482092b9552ae9442a80
- 出典データセット
- uspto-grants-1995_02
- 特許番号
- US05391771
反応ノート
読み込み中…