Sodium Thiosulfate → HCID 10522826、化合物

反応式

[Br:1]N1C(=O)CCC1=O.S([O-])([O-])(=O)=S.[Na+].[Na+].[Br:16][CH2:17][CH2:18][C:19]1[CH:24]=[CH:23][C:22]([NH:25][CH2:26][C:27]([O:29][CH2:30][CH3:31])=[O:28])=[CH:21][CH:20]=1>>[Br:1][C:23]1[CH:24]=[C:19]([CH2:18][CH2:17][Br:16])[CH:20]=[CH:21][C:22]=1[NH:25][CH2:26][C:27]([O:29][CH2:30][CH3:31])=[O:28]

参加物

反応物 3

HCID 24477Sodium Thiosulfate

HCID 67184N-bromobutanimide

HCID 18316767HCID 18316767、化合物

生成物 1

HCID 10522826HCID 10522826、化合物

実験手順

Ethyl N-[2-bromo-4-(2-bromoethyl)phenyl]aminoacetate was prepared according to a similar manner to that described in Reference Example 6 using 1 molar equivalent of both N-bromosuccinimide and 0.4M aqueous sodium thiosulfate solution to ethyl N-[4-(2-bromo-ethyl)phenyl]aminoacetate.

出典と根拠

ORDレコード: ord-a776ebb3fa984799a06339ef4be3f49b
出典データセット: uspto-grants-2002_03
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06353025B1

反応ノート

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