Benzene → HCID 23322207、化合物

HRID 280360

反応式

HRID 280360 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([OH:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].C1C=CC=CC=1.[OH-].[CH2:18]([N+:20]([CH2:25][CH3:26])([CH2:23][CH3:24])[CH2:21][CH3:22])[CH3:19]>O>[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([O-:10])=[CH:6][CH:5]=1)([O-:3])=[O:2].[CH2:18]([N+:20]([CH2:25][CH3:26])([CH2:23][CH3:24])[CH2:21][CH3:22])[CH3:19]

参加物

5

反応物 3

HCID 241BenzeneHCID 9804-NitrophenolHCID 6509Tetraethylammonium Hydroxide

生成物 1

HCID 23322207HCID 23322207、化合物収率 94.7%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture of 4-nitrophenol (13.9 g, 0.10 mol) and benzene (250 mL) was treated with tetraethylammonium hydroxide (14.7 g, 0.10 mol), added as a 20% aqueous solution. The mixture was heated under reflux until all water was removed by azeotropic distillation. The solution was allowed to cool with continued stirring. Upon standing, 25.4 g of a yellow solid was obtained; it was recrystallized from THF. 1H NMR (CDCl3) confirmed the title compound.

後処理

  1. temperatureThe mixture was heated
  2. customwas removed by azeotropic distillation
  3. temperatureto cool with continued stirring

出典と根拠

ORDレコード
ord-ee8ea755095f40dfa79c74726b8d381f
出典データセット
uspto-grants-1986_05
特許番号
US04588795

関連ノート

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