テトラエチルアンモニウムヒドロキシド (10%水溶液)

Tetraethylammonium Hydroxide

HCID 6509CAS 77-98-5

基本情報

標準SMILES
CC[N+](CC)(CC)CC.[OH-]
InChIKey
LRGJRHZIDJQFCL-UHFFFAOYSA-M
分子式
C8H20N.HO
平均分子量
147.26 g/mol
単同位体質量
147.16231429

概要

See also: Tetraethylammonium (has active moiety).

名称と識別子

優先名称
Tetraethylammonium Hydroxide
IUPAC
tetraethylazanium hydroxide
現地名
テトラエチルアンモニウムヒドロキシド (10%水溶液)
英語名
Tetraethylammonium hydroxide
分子式
C8H21NO
分子量
147.26

名称と別名

Tetraethylammonium hydroxide77-98-5Tetraethyl ammonium hydroxideRA8VU41B1FETHANAMINIUM, N,N,N-TRIETHYL-, HYDROXIDEDTXSID30883222RefChem:188566Hydroxide, TetraethylammoniumDTXCID901022771201-073-3Ammonium, tetraethyl-, hydroxidetetraethylazanium;hydroxide
名称をさらに表示
テトラエチルアンモニウムヒドロキシド (10%水溶液)テトラエチルアンモニウムヒドロキシド (10%水溶液) [IPC試薬]テトラエチルアンモニウムヒドロキシドN,N,N-トリエチルエタンアミニウム·ヒドロキシドテトラエチルアミニウム·ヒドロキシドテトラエチルアンモニウム·ヒドロキシドテトラエチルアンモニウム ヒドロキシド水酸化テトラエチルアンモニウム水酸化テトラエチルアンモニウムメタノール溶液水酸化テトラエチルアンモニウム溶液テトラエチルアンモニウムヒドロキシド (35%水溶液)N,N,N-トリエチルエタンアミニウム=ヒドロキシドテトラエチルアンモニウムヒドロキシド 10%水溶液水酸化テトラエチルアンモニウム 溶液テトラエチルアンモニウム・ヒドロキシドN,N,N-トリエチルエタンアミニウム・ヒドロキシドテトラエチルアミニウム・ヒドロキシドTEA HYDROXIDETetraethylammoniumhydroxidtetraethyl-ammoniuhydroxideTetraethylamminonium hydroxiden,n,n-triethyl-ethanaminiuhydroxidetetraethylammoniumhydroxide,solutionEthanaminum,N,N,N-triethyl-,hydroxidetetraethylammonioumhydroxide(aqueous)Ethanaminium,N,N,N-triethyl-,hydroxideTetraethylaMMoniuM hydroxide ,25% [25 wt. % in H2O]
UNII-RA8VU41B1Fn,n,n-triethylethanaminium hydroxideEINECS 201-073-3AI3-24479MFCD00009024EC 201-073-3Tetraethylammonium hydroxide (10% in Water)77-98-5(water)

データベース識別子

CAS
77-98-5
PubChem CID
6509
DTXSID
DTXSID30883222
UNII
RA8VU41B1F
EC Number
201-073-3

物性

構造計算による物性

極性表面積
1 Ų
水素結合供与体数
1
水素結合受容体数
1
回転可能結合数
4
重原子数
10

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Quaternary Amines
Physical Description · 2 件

Liquid

Aqueous solution: Colorless odorless liquid; [Merck Index] 35% Aqueous solution: Colorless to pale yellow liquid; [Alfa Aesar MSDS]

物理化学的性質

融点
-98 C · -98C
沸点
110 °C · 110 °C
比重(密度)
1.023 g/mL · 1.023 g/mL at 25 °C
屈折率
20 · n20/D 1.422
闪点
11 °C · 11 °C
貯蔵温度
2 · 2-8°C

化学的性質

化学的特性colourless liquid

安全と法規制

GHS分類

GHS Classification · 6 件

Danger

H290 (15.3%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P262, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P308+P316, P316, P317, P319, P321, P330, P361+P364, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 301 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

危険有害性情報

Regulatory Information · 4 件

Chemical: Ethanaminium, N,N,N-triethyl-, hydroxide

Ethanaminium, N,N,N-triethyl-, hydroxide (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethanaminium, N,N,N-triethyl-, hydroxide (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 09-10-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10763

Ethanaminium, N,N,N-triethyl-, hydroxide: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Ethanaminium, N,N,N-triethyl-, hydroxide: Human health tier II assessment
Hazards Summary · 1 件

Subcutaneous LDLo (mouse) = 107 mg/kg; [RTECS] The free base exists only in solution or as hydrates; A strong base that absorbs carbon dioxide from the air; [Merck Index] 35% Aqueous solution: Causes burns; [Alfa Aesar MSDS] See Tetraethylammonium bromide.

Hazard Classes and Categories · 2 件

Met. Corr. 1 (15.3%)

Acute toxicity (ingestion) - category 4

安全と保護具

Protective Action Criteria (PAC) · 3 件

0.90 [mg/m3]

9.9 [mg/m3]

59 [mg/m3]

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F
9-34
wgk
3
tsca
TSCA listed
rtecs
KH3150000
ridadr
UN 3286 3/PG 2
hs_code
29239000

化学と産業

薬理情報

MeSH Pharmacological ClassificationA class of drugs that act by inhibition of potassium efflux through cell membranes. Blockade of potassium channels prolongs the duration of ACTION POTENTIALS. They are used as ANTI-ARRHYTHMIA AGENTS and VASODILATOR AGENTS.

用途と製造

U.S. Production2023: 1,000,000 - <5,000,000 lb
Industry UsesPlating agent
General Manufacturing Information · 2 件

All Other Basic Inorganic Chemical Manufacturing

Ethanaminium, N,N,N-triethyl-, hydroxide (1:1): ACTIVE

応用分野 · 2 件

使用Tetraethylammonium hydroxide is a strong organic base and finds applications in photovoltaic chemicals, advanced ceramics, flat panel display chemicals, selective etching and transesterification catalysts. Its solution (35 wt. % in H2O) may be used as an organic structure-directing agent (SDA)/template in the synthesis of mesoporous molecular sieves and zeolite samples.

一般的な説明The product is 20wt.% solution of tetraethylammonium hydroxide (TEA hydroxide, TENOH) in H2O. TEA hydroxide is a quaternary ammonium hydroxide (QAH). It participates in the synthesis of zeolite beta. TENOH peptized titania aqueous sols have been employed in the preparation of nanocrystalline anatase films.

関連反応

27 件

関連ノート

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