Dimethylformamide → N,N,N,2,2-Pentamethylpropan-1-aminium iodide

反応式

[CH2:1](N)[C:2](C)([CH3:4])[CH3:3].[CH2:7](N(CCCC)CCCC)CCC.C[I:21].[CH3:22][N:23]([CH:25]=O)[CH3:24]>>[I-:21].[CH3:22][N+:23]([CH2:25][C:2]([CH3:4])([CH3:3])[CH3:1])([CH3:7])[CH3:24]

参加物

反応物 4

HCID 6228Dimethylformamide

HCID 6328Methyl iodide

HCID 7622Tributylamine

HCID 79882Neopentylamine

生成物 1

HCID 13652289N,N,N,2,2-Pentamethylpropan-1-aminium iodide

実験手順

11.51 Grams of neopentylamine (Aldrich), 48.7 grams of tributyl amine and 100 ml of DMF were mixed and cooled. 56 Grams of methyl iodide (Aldrich) were added dropwise and the reaction was carried out and worked up as in Example 1.

後処理

temperaturecooled

出典と根拠

ORDレコード: ord-c51cb8b2898444f0a0cd172d02f82682
出典データセット: uspto-grants-1986_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04589977

反応ノート

読み込み中…