Oxalyl chloride → 2,3-Dichloro-6-iodobenzoic acid chloride

HRID 321995

反応式

HRID 321995 の反応式
[Cl:1][C:2]1[C:10]([Cl:11])=[CH:9][CH:8]=[C:7]([I:12])[C:3]=1[C:4](O)=[O:5].C(Cl)(=O)C([Cl:16])=O>CN(C=O)C.C(OCC)(=O)C>[Cl:1][C:2]1[C:10]([Cl:11])=[CH:9][CH:8]=[C:7]([I:12])[C:3]=1[C:4]([Cl:16])=[O:5]

参加物

5

反応物 2

HCID 65578Oxalyl chlorideHCID 220088162,3-Dichloro-6-iodobenzoic acid

生成物 1

HCID 542920312,3-Dichloro-6-iodobenzoic acid chloride

試薬・触媒・溶媒 2

HCID 6228Dimethylformamide触媒HCID 8857Ethyl Acetate溶媒

実験手順

DMF (one drop) was added to a stirred solution of 2,3-dichloro-6-iodobenzoic acid (1.53 g, 4.83 mmol) and oxalyl chloride (2 ml) in ethyl acetate (20 ml). After 2 hours, the solution was evaporated and the product was used immediately.

後処理

  1. customthe solution was evaporated

出典と根拠

ORDレコード
ord-7726a461dd284d93b0a1fcdd654e9b25
出典データセット
uspto-grants-2001_04
特許番号
US06211189B1

関連ノート

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