Benzylamine → GlyTouCan:G63996AI

HRID 332916

反応式

HRID 332916 の反応式
[CH3:1][C:2]([O:4][CH2:5][C@H:6]1[O:11][C@@H:10]([O:12]C(C)=O)[C@H:9]([O:16][C:17]([CH3:19])=[O:18])[C@@H:8]([O:20][C:21]([CH3:23])=[O:22])[C@H:7]1[O:24][C:25]([CH3:27])=[O:26])=[O:3].C(N)C1C=CC=CC=1>C1COCC1>[C:17]([O:16][C@@H:9]1[C@@H:8]([O:20][C:21](=[O:22])[CH3:23])[C@@H:7]([O:24][C:25](=[O:26])[CH3:27])[C@@H:6]([CH2:5][O:4][C:2](=[O:3])[CH3:1])[O:11][C@H:10]1[OH:12])(=[O:18])[CH3:19]

参加物

4

反応物 2

HCID 7504BenzylamineHCID 94752beta-D-Galactose pentaacetate

生成物 1

HCID 11152232GlyTouCan:G63996AI

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

The synthesis of compound 9 is illustrated in FIG. 6. 20 g (51.24 mmol) of β-D-galactosepentaacetate 1 was dissolved in 150 ml THF and 6.7 ml (61.49 mmol) of benzylamine was added with a dropping funnel. The reaction was stirred for 18 h at room temperature to give 2,3,4,6-tetra-O-acetyl-β-D-galactopyranose 2.

出典と根拠

ORDレコード
ord-9208ea680a3d4041996f1373e850ba66
出典データセット
uspto-grants-2014_11
特許番号
US08877917B2

関連ノート

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