Benzenamine, 2-phenoxy- → 1-Isothiocyanato-2-phenoxybenzene

HRID 349384

反応式

HRID 349384 の反応式
[C:1](C1NC=CN=1)(C1NC=CN=1)=[S:2].[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[NH2:22])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C1COCC1>[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[N:22]=[C:1]=[S:2])[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

参加物

4

反応物 2

HCID 75899Benzenamine, 2-phenoxy-HCID 11412697Thiocarbonyl diimidazole

生成物 1

HCID 220404391-Isothiocyanato-2-phenoxybenzene

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

1.96 g (0.011 mol) of thiocarbonyl diimidazole were added to a solution of 1.85 g (0.01 mol) of 2-phenoxyaniline in 50 ml of THF and the mixture was stirred at room temperature for 4 hours, giving, after removal of the solvent by distillation, the compound as a brown amorphous product.

後処理

  1. customgiving
  2. customafter removal of the solvent
  3. distillationby distillation

出典と根拠

ORDレコード
ord-853bee71781a42c6a85dc3d3c78adb8d
出典データセット
uspto-grants-2007_02
特許番号
US07179829B2

関連ノート

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