Methylhydrazine → N-cyano-1-methylhydrazinecarboximidothioic acid methyl ester

HRID 35049

反応式

HRID 35049 の反応式
[CH3:1][NH:2][NH2:3].[CH3:4][S:5][C:6](SC)=[N:7][C:8]#[N:9]>C(#N)C>[C:8]([N:7]=[C:6]([N:2]([CH3:1])[NH2:3])[S:5][CH3:4])#[N:9]

参加物

4

反応物 2

HCID 6061MethylhydrazineHCID 66289Dimethyl N-cyanodithioiminocarbonate

生成物 1

HCID 86738283N-cyano-1-methylhydrazinecarboximidothioic acid methyl ester

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

A mixture of methyl hydrazine (0.48 ml) and cyanocarbonimidodithioic acid dimethyl ester (1.3 g) in acetonitrile was stirred at 25° for 16 hours. The resulting solution was evaporated to a gum which was crystallised from acetonitrile/ether to give the title compound as colourless granules (210 mg) m.p. 69°-71°.

後処理

  1. customThe resulting solution was evaporated to a gum which
  2. customwas crystallised from acetonitrile/ether

出典と根拠

ORDレコード
ord-3d31bfcbc0f843ba9ecffef034de6c02
出典データセット
uspto-grants-1988_08
特許番号
US04764612

関連ノート

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