Hexane → cis-Stilbene

HRID 351960

反応式

HRID 351960 の反応式
[C:1]1([C:7]#[C:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CCCCCC>C1COCC1>[C:1]1(/[CH:7]=[CH:8]\[C:9]2[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

4

実験手順

In the foregoing epititanations of diphenylacetylene conducted in THF or hexane, parallel epititanations were conducted in the same manner but the hydrolytic workup in each case was performed with 3N DCl in D2O. In these experiments the cis-stilbene isolated was >98% dideuteriated at the vinylic carbon atoms (12).

出典と根拠

ORDレコード
ord-9507fa7fcc184888bfcbd3570c598bd7
出典データセット
uspto-grants-2004_06
特許番号
US06743872B1

関連ノート

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