Potassium ethylxanthate → HCID 20736364、化合物
反応式
Br[CH:2]([C:4]1[O:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[N:8]=1)[CH3:3].[K+].[CH2:13]([O:15][C:16]([S-:18])=[S:17])[CH3:14]>C(#N)C>[CH2:13]([O:15][C:16](=[S:17])[S:18][CH:2]([C:4]1[O:5][C:6](=[O:11])[C:7]([CH3:10])([CH3:9])[N:8]=1)[CH3:3])[CH3:14]参加物
4
実験手順
To a solution of 2-(1-bromo-ethyl)-4,4dimethyl-4H-oxazol-5-one (3.00 g; 13.6 mmol) and 50 mL acetonitrile was added O-ethyl xanthic acid potassium salt (2.18 g; 13.6 mmol). The mixture was stirred under a nitrogen atmosphere at room temperature for 5 hours. The reaction mixture was filtered and the solid was washed with 10 mL acetontrile 10 mL. The combined filtrate was concentrated under reduced pressure to afford 2.89 g (81%) of dithiocarbonic acid S-[1-(4,4-dimethyl-5-oxo-4,5-dihydro-oxazol-2-yl)-ethyl] ester O-ethyl ester as a yellow oil.