Hydroquinone → 4-(4-acryloxybutoxy)benzoic acid

HRID 355598

反応式

HRID 355598 の反応式
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:15]=[CH:14][C:10]([C:11]([OH:13])=[O:12])=[CH:9][CH:8]=1.[C:16](O)(=[O:19])[CH:17]=[CH2:18].C1(C=CC(O)=CC=1)O.C1(C)C=CC(S(O)(=O)=O)=CC=1>ClC(Cl)(Cl)C>[C:16]([O:1][CH2:2][CH2:3][CH2:4][CH2:5][O:6][C:7]1[CH:15]=[CH:14][C:10]([C:11]([OH:13])=[O:12])=[CH:9][CH:8]=1)(=[O:19])[CH:17]=[CH2:18]

参加物

6

反応物 4

HCID 785HydroquinoneHCID 6101p-Toluenesulfonic acidHCID 6581Acrylic AcidHCID 152185964-(4-Hydroxybutoxy)benzoic acid

生成物 1

HCID 110327354-(4-acryloxybutoxy)benzoic acid

試薬・触媒・溶媒 1

HCID 62781,1,1-Trichloroethane溶媒

実験手順

A solution of (1) (282 g; 1.34 mol), freshly distilled acrylic acid (230 ml; 3.35 mol), hydroquinone (1.9 g) and p-toluenesulfonic acid (23.7 g) in 1,1,1-trichloroethane (1.1 l) is refluxed for 10 hours. The reaction mixture is cooled to from 60° to 70° C. and stirred into 2.5 l of petroleum ether, and the precipitate is filtered off, washed with petroleum ether and dried at room temperature under reduced pressure for 24 hours.

後処理

  1. temperatureThe reaction mixture is cooled to from 60° to 70° C.
  2. filtrationthe precipitate is filtered off
  3. washwashed with petroleum ether
  4. customdried at room temperature under reduced pressure for 24 hours

出典と根拠

ORDレコード
ord-2ec6ac0b8cc247aa84856d01f6ecf9ff
出典データセット
uspto-grants-1998_11
特許番号
US05833880

関連ノート

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