Diisopropyl Ether → (R)-2-bromo-1-(3-chlorophenyl)ethanol

HRID 357724

反応式

HRID 357724 の反応式
C(OC(C)C)(C)C.[Br:8][CH2:9][CH:10]([C:12]1[CH:17]=[CH:16][CH:15]=[C:14]([Cl:18])[CH:13]=1)[OH:11]>>[Br:8][CH2:9][C@@H:10]([C:12]1[CH:17]=[CH:16][CH:15]=[C:14]([Cl:18])[CH:13]=1)[OH:11]

参加物

3

反応物 2

HCID 7914Diisopropyl EtherHCID 99646942-Bromo-1-(3-chlorophenyl)ethanol

生成物 1

HCID 11075396(R)-2-bromo-1-(3-chlorophenyl)ethanol

実験手順

Diisopropyl ether was added to a mixture of 100 mg (0.4 mmol) of 2-bromo-1-(3-chlorophenyl)ethanol, 20 mg of TOYOCHIMU LIP (available from Toyobo Co., Ltd.) and 0.3 mmol of each of the various acid anhydrides shown in Table 3 was to make the total volume to 1 ml. These reaction mixtures were respectively allowed to undergo reaction at a temperature of 27° C. for 98 hours. The results are set forth in Table 3.

後処理

  1. customThese reaction mixtures
  2. customreaction at a temperature of 27° C. for 98 hours

出典と根拠

ORDレコード
ord-8af97dab936b4dbda8044b95a5688946
出典データセット
uspto-grants-1998_11
特許番号
US05841001

関連ノート

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