Phenyl Isothiocyanate → HCID 20155092、化合物
反応式
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]2[N:12]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[N:11]=[C:10]([C:19]3[CH:24]=[CH:23][C:22]([O:25][CH3:26])=[CH:21][CH:20]=3)[CH2:9]2)=[CH:4][CH:3]=1.[C:27]1([N:33]=[C:34]=[S:35])[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1>C(#N)C>[CH3:26][O:25][C:22]1[CH:21]=[CH:20][C:19]([C:10]2[CH2:9][CH:8]([C:5]3[CH:6]=[CH:7][C:2]([NH:1][C:34]([NH:33][C:27]4[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=4)=[S:35])=[CH:3][CH:4]=3)[N:12]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[N:11]=2)=[CH:24][CH:23]=1参加物
4
実験手順
3.4 g of 5-(4-aminophenyl)-3-(4-methoxyphenyl)-1-phenyl-2-pyrazoline and 1.5 g of phenyl isothiocyanate were reacted in acetonitrile for 5 hours at room temperature, and the product was reprecipitated from 30 ml of dimethylformamide-methanol to obtain 2.7 g of the desired end compound. m.p. 153°-156° C.
後処理
- customthe product was reprecipitated from 30 ml of dimethylformamide-methanol