Water → (2,6-Dimethyl-3-nitrophenyl)methanol

HRID 365559

反応式

HRID 365559 の反応式
C([O:4][CH2:5][C:6]1[C:11]([CH3:12])=[CH:10][CH:9]=[C:8]([N+:13]([O-:15])=[O:14])[C:7]=1[CH3:16])(=O)C.[OH-].[Na+].O>CO>[CH3:16][C:7]1[C:8]([N+:13]([O-:15])=[O:14])=[CH:9][CH:10]=[C:11]([CH3:12])[C:6]=1[CH2:5][OH:4]

参加物

5

反応物 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 10537042(2,6-Dimethyl-3-nitrophenyl)methyl acetate

生成物 1

HCID 10487641(2,6-Dimethyl-3-nitrophenyl)methanol収率 82.4%

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

To a solution of 2,6-dimethyl-3-nitrobenzyl acetate (26.9 g) in methanol (266 ml) was added aqueous 1N sodium hydroxide solution (133 ml) at ambient temperature for 30 minutes. To the mixture was added water, and the precipitate was collected by filtration to give 2,6-dimethyl-3-nitrobenzyl alcohol (18.0 g) as pale yellow crystals.

後処理

  1. filtrationthe precipitate was collected by filtration

出典と根拠

ORDレコード
ord-f1fb1725b3bb469d9f57f73a62124038
出典データセット
uspto-grants-2000_10
特許番号
US06127389

関連ノート

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