1,3-Diacetylbenzene → alpha1,alpha3-Dimethyl-1,3-benzenedimethanol

HRID 373758

反応式

HRID 373758 の反応式
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([C:10](=[O:12])[CH3:11])[CH:5]=1)(=[O:3])[CH3:2].[BH4-].[Na+]>>[CH3:11][CH:10]([C:6]1[CH:7]=[CH:8][CH:9]=[C:4]([CH:1]([CH3:2])[OH:3])[CH:5]=1)[OH:12]

参加物

3

反応物 2

HCID 232291,3-DiacetylbenzeneHCID 4311764Sodium borohydride

生成物 1

HCID 15148377alpha1,alpha3-Dimethyl-1,3-benzenedimethanol

実験手順

This mixture of stereoisomers was prepared from 1,3-diacetylbenzene by reduction with sodium borohydride as described above for the para stereoisomers. The mixture of stereoisomers was isolated as a semisolid. It appeared as a single spot on TLC and as a single peak on VPC.

後処理

  1. additionThis mixture of stereoisomers
  2. additionThe mixture of stereoisomers
  3. customwas isolated as a semisolid

出典と根拠

ORDレコード
ord-546ecb5962634cd395c40460dcb9740d
出典データセット
uspto-grants-1992_11
特許番号
US05166062

関連ノート

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