Styrene → Styrene-butadiene-styrene

HRID 376474

反応式

HRID 376474 の反応式
[CH2:1]1[CH2:6]CC[CH2:3][CH2:2]1.[CH2:7]=[CH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C([Li])CCC.C=CC=C>O1CCCC1>[CH2:7]=[CH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[CH2:6]=[CH:1][CH:2]=[CH2:3].[CH2:7]=[CH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

参加物

6

反応物 4

HCID 7501Styrene2 回HCID 78451,3-ButadieneHCID 8078CyclohexaneHCID 178418339Butyllithium

生成物 1

HCID 22280236Styrene-butadiene-styrene

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

In a 2 gallon autoclave reactor, 4,500 g of cyclohexane was placed. 9 g of tetrahydrofuran, 112.5 g of styrene monomer and 1.6 g of n-butyllithium were charged into the reactor and then the reaction mixture was subjected to polymerization for 1 hour. Thereafter, 525 g of 1,3-butadiene monomer were injected into the reactor to polymerize for one hour. Finally, 112.5 g of styrene monomer was added and then polymerized for one hour to obtain styrene-butadiene-styrene living block copolymer with a number average molecular weight of about 60,000 which had a styrene content of 30.54% (block styrene content of 30.3%) and 1,2-vinyl bond content of 39.80% (27.8% when reduced into whole polymer). Living lithium in the polymer was present in an amount of 1.67 mmol per 100 g of polymer.

後処理

  1. customthe reaction mixture was subjected to polymerization for 1 hour
  2. customto polymerize for one hour
  3. custompolymerized for one hour

出典と根拠

ORDレコード
ord-b0b4f16fa166401598cc7b31c770170f
出典データセット
uspto-grants-2000_02
特許番号
US06020439

関連ノート

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