Allyl bromide → 2-(2-(Allyloxy)ethoxy)ethanol

HRID 37732

反応式

HRID 37732 の反応式
[CH2:1](Br)[CH:2]=[CH2:3].[CH2:5]([OH:11])[CH2:6][O:7][CH2:8][CH2:9][OH:10]>C1COCC1.[H-].[Na+]>[CH2:1]([O:11][CH2:5][CH2:6][O:7][CH2:8][CH2:9][OH:10])[CH:2]=[CH2:3]

参加物

4

反応物 2

HCID 7841Allyl bromideHCID 8117Diethylene Glycol

生成物 1

HCID 847772-(2-(Allyloxy)ethoxy)ethanol収率 82%

試薬・触媒・溶媒 1

HCID 23694757NaH THF溶媒

実験手順

Diethylene glycol monoallyl ether was prepared by reacting allyl bromide with excess diethylene glycol in THF-NaH (tetrahydrofuran-sodium hydride). The product was obtained in 82% yield after distillation. b.p.=96-99° C./7 mmHg.

後処理

  1. customThe product was obtained in 82% yield
  2. distillationafter distillation

出典と根拠

ORDレコード
ord-4e69885985a74b1ca4a5f8fc798f2882
出典データセット
uspto-grants-2013_09
特許番号
US08524104B1

関連ノート

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