Sodium Hydroxide → Oleylamine

HRID 381806

反応式

HRID 381806 の反応式
[C:1](#[N:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH-].[Na+]>O>[CH2:1]([NH2:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 6420241(Z)-9-Octadecenenitrile

生成物 1

HCID 5356789Oleylamine収率 94%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

300 g of oleonitrile were fed into a 1 liter autoclave and 2 g of Catalyst A, 6 g of water and 0.5 g of 48% sodium hydroxide were put thereinto. After purging with nitrogen gas, the reaction was carried out under the hydrogen pressure of 1.0 MpaG at the reaction temperature of 130° C. The reaction-finishing point was determined at the point where the hydrogen gas was no longer absorbed. The reaction system was aged further for 15 minutes. Absorption of hydrogen gas proceeded smoothly and the absorption was completed in 1.3 hour. After finish of the reaction and aging, the reaction product was taken out from the reactor and the catalyst was removed off. Then, the reaction product was distilled and purified under 0.27 kPa at 220° C. Oleylamine was obtained with yield of 94%.

後処理

  1. customAfter purging with nitrogen gas
  2. customwas carried out under the hydrogen pressure of 1.0 MpaG at the reaction temperature of 130° C
  3. customno longer absorbed
  4. customAbsorption of hydrogen gas
  5. customthe absorption
  6. waitwas completed in 1.3 hour
  7. customAfter finish of the reaction
  8. customthe catalyst was removed off
  9. distillationThen, the reaction product was distilled
  10. custompurified under 0.27 kPa at 220° C

出典と根拠

ORDレコード
ord-16a236bf04b84b9e815c4382b755a4ee
出典データセット
uspto-grants-2001_10
特許番号
US06307104B1

関連ノート

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