Chloroform → CCl3CF2CHFCF3

HRID 41731

反応式

HRID 41731 の反応式
[F:1][C:2]([F:9])([F:8])[C:3]([F:7])=[C:4]([F:6])[F:5].[CH:10]([Cl:13])([Cl:12])[Cl:11]>>[C:10]([C:4]([CH:3]([C:2]([F:9])([F:8])[F:1])[F:7])([F:6])[F:5])([Cl:13])([Cl:12])[Cl:11]

参加物

3

反応物 2

HCID 6212ChloroformHCID 8302Hexafluoropropylene

生成物 1

HCID 12829385CCl3CF2CHFCF3

反応条件

温度
290 °C

実験手順

A 0.5 inch (12.7 mm) by 40 inch (101.6 cm) plug flow reactor that is packed with Helipack Monel support is heated to 290° C. A 50/50 (molar %) mixture of hexafluoropropene and chloroform is fed into the reactor at about 1.5 g/min. The reactor pressure is maintained at 100 psig. The effluent from the reactor is fed into a distillation column and the unreacted reagents removed by distillation and recycled. The product CCl3CF2CHFCF3 is used in the next reaction.

後処理

  1. temperatureThe reactor pressure is maintained at 100 psig
  2. distillationThe effluent from the reactor is fed into a distillation column
  3. customthe unreacted reagents removed by distillation
  4. customThe product CCl3CF2CHFCF3 is used in the next reaction

出典と根拠

ORDレコード
ord-e25e851eb2fd41f9bfbe6fa77cb92408
出典データセット
uspto-grants-2013_09
特許番号
US08530709B2

関連ノート

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