Formaldehyde → p-Tert-octylphenol phenol formaldehyde

反応式

[C:1]([C:9]1[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:3])[CH3:2].C=O.O.O.C(O)(=O)[C:21](O)=[O:22].[C:26]1([OH:32])[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1>>[C:1]([C:9]1[CH:10]=[CH:11][C:12]([OH:15])=[CH:13][CH:14]=1)([CH2:4][C:5]([CH3:8])([CH3:7])[CH3:6])([CH3:2])[CH3:3].[C:26]1([OH:32])[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1.[CH2:21]=[O:22]

参加物

反応物 4

HCID 712Formaldehyde3 回

HCID 996Phenol

HCID 88144-Tert-octylphenol2 回

HCID 61373Oxalic acid dihydrate

生成物 1

HCID 169941p-Tert-octylphenol phenol formaldehyde

反応条件

温度: 100 °C

実験手順

206 g (1 mole) of p-tert-octylphenol, 59.0 g (1.57 moles) of 80% paraformaldehyde and 5.0 g of oxalic acid dihydrate were reacted under water reflux (100° C.) for 10 hours in a glass reactor to form a reaction intermediate. Ten hours after the initiation of the reaction, 89% of the used formaldehyde was consumed,and 1.32 moles of the formaldehyde added to 1.0 mole of p-tert-octylphenol. Phenol (70.5 g; 0.75 mole) was added to the reaction intermediate, and reacted at 100° C. for 3 hours. The reaction mixture was dehydrated by heating it to 165° C. under atmospheric pressure and then under reduced pressure to give a pale-colored p-tert-octylphenol/phenol/formaldehyde co-condensate.