Iodoethane → Ethyl (5-ethyl-2-pyridyl)carbamodithioate

HRID 441292ノート

反応式

HRID 441292 の反応式
[CH2:1](C1C=CC(N)=NC=1)[CH3:2].C(=S)=S.[CH2:13]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22]([S-:24])=[S:23])=[N:19][CH:20]=1)[CH3:14].C([NH+](CC)CC)C.C(I)C>C(#N)C.C(N(CC)CC)C>[CH2:13]([C:15]1[CH:16]=[CH:17][C:18]([NH:21][C:22]([S:24][CH2:1][CH3:2])=[S:23])=[N:19][CH:20]=1)[CH3:14]

参加物

7

反応物 4

HCID 6340IodoethaneHCID 6348Carbon DisulfideHCID 98127775-Ethylpyridin-2-amineHCID 86734976Triethylammonium (5-ethyl-2-pyridyl)carbamodithioate

生成物 1

HCID 54021047Ethyl (5-ethyl-2-pyridyl)carbamodithioate

試薬・触媒・溶媒 2

HCID 6342Acetonitrile溶媒HCID 8471Triethylamine溶媒

実験手順

Following a procedure similar to that described in Example 1 above, 5-ethyl-2-aminopyridine [Ban et al., Chem. Ind. (London) 1964 (17), 710-711] is reacted with carbon disulfide and triethylamine in acetonitrile and the resulting triethylammonium (5-ethyl-2-pyridyl)carbamodithioate rected with ethyl iodide to give ethyl (5-ethyl-2-pyridyl)carbamodithioate.

出典と根拠

ORDレコード
ord-4d483e6ebdb7428793380a43d6aa3849
出典データセット
uspto-grants-1977_08
特許番号
US04039550

反応ノート

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