Phenyl phenylglyoxylate → Phenyl 4-chlorobenzoate

HRID 443086

反応式

HRID 443086 の反応式
[C:1]1([C:7](=O)[C:8]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3]C=1.C1(C(=O)C(OC2C=CC([Cl:34])=CC=2)=O)C=CC=CC=1>[Cl-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)Cl>[Cl:34][C:5]1[CH:4]=[CH:3][C:7]([C:8]([O:10][C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=2)=[O:9])=[CH:1][CH:6]=1

参加物

5

反応物 2

HCID 13975017Phenyl phenylglyoxylateHCID 544420204-Chlorophenyl phenylglyoxylate

生成物 1

HCID 260766Phenyl 4-chlorobenzoate

試薬・触媒・溶媒 2

HCID 164911Tetraphenylphosphonium Chloride触媒HCID 6212Chloroform溶媒

実験手順

The decarbonylation reaction of Example 79 was repeated except that phenyl phenylglyoxylate (PPG) was replaced with 4-chlorophenyl phenylglyoxylate (4-CPPG), and that the amounts of tetraphenylphosphonium chloride and chloroform were changed as set forth in Table 13. The results are set forth in Table 13.

後処理

  1. customThe decarbonylation reaction of Example 79

出典と根拠

ORDレコード
ord-b4c01714edc043b29f69990524dc94d0
出典データセット
uspto-grants-1999_04
特許番号
US05892091

関連ノート

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