1-Methylimidazole → 1-Methyl-3-propylimidazolium Iodide

HRID 449241ノート

反応式

HRID 449241 の反応式
[CH3:1][N:2]1[CH:6]=[CH:5][N:4]=[CH:3]1.[CH2:7]([I:10])[CH2:8][CH3:9]>C1(C)C=CC=CC=1>[I-:10].[CH3:1][N+:2]1[CH:6]=[CH:5][N:4]([CH2:7][CH2:8][CH3:9])[CH:3]=1

参加物

4

反応物 2

HCID 13901-MethylimidazoleHCID 336431-Iodopropane

生成物 1

HCID 129710081-Methyl-3-propylimidazolium Iodide

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

1-Methylimidazole (8.2 g, made by Aldrich) and propyl iodide (16.9 g, made by Kanto Chemical) were stirred in toluene at 75° C. for 15 hours. After the end of the reaction, the reaction solution separated into the two layers of a toluene layer and an ionic liquid layer. By removing the toluene layer from the reaction solution, the ionic liquid was obtained. The ionic liquid obtained was washed with toluene 3 times for purification. The toluene was distilled off in vacuo, whereby an ionic liquid 1-methyl-3-propylimidazolium iodide (23.8 g) was obtained.

後処理

  1. customAfter the end of the reaction
  2. customthe reaction solution separated into the two layers of a toluene layer
  3. customBy removing the toluene layer from the reaction solution
  4. customthe ionic liquid was obtained
  5. customThe ionic liquid obtained
  6. washwas washed with toluene 3 times for purification
  7. distillationThe toluene was distilled off in vacuo, whereby an ionic liquid 1-methyl-3-propylimidazolium iodide (23.8 g)
  8. customwas obtained

出典と根拠

ORDレコード
ord-a290ab05dd754b4ea28be7e14d41d2cb
出典データセット
uspto-grants-2013_07
特許番号
US08481849B2

反応ノート

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