Chlorotrimethylsilane → (Hexyloxy)trimethylsilane

HRID 463363

反応式

HRID 463363 の反応式
[CH2:1]([OH:7])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH3:8][Si:9]([CH3:12])([CH3:11])Cl.C[Si](C)(C)NCCN[Si](C)(C)C>ClCCl>[CH2:1]([O:7][Si:9]([CH3:12])([CH3:11])[CH3:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

参加物

5

反応物 3

HCID 6397ChlorotrimethylsilaneHCID 81031-HexanolHCID 74569N,N'-Bis(trimethylsilyl)ethylenediamine

生成物 1

HCID 519489(Hexyloxy)trimethylsilane収率 59%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

To hexan-1-ol (5.1 g, 0.05 mole) in dichloromethane (50 ml) were added trimethylchlorosilane (1.81 g, 0.0166 mole) and N,N'-bis(trimethylsilyl)ethlenediamine (3.44 g, 0.0166 mole). The mixture was stirred under reflux for 30 minutes, filtered and the solvent removed. The residue, hexanoxytrimethylsilane, was obtained in 59% yield (5.15 g).

後処理

  1. temperatureunder reflux for 30 minutes
  2. filtrationfiltered
  3. customthe solvent removed

出典と根拠

ORDレコード
ord-492d73126dca42c6956bc86f6ab2124b
出典データセット
uspto-grants-1985_05
特許番号
US04518787

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