1,2-Dinitrobenzene → HCID 13292704、化合物

HRID 463551

反応式

HRID 463551 の反応式
[N+]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[N+:10]([O-:12])=[O:11])([O-])=O.[CH3:13][P:14]([O:18]CC)[O:15][CH2:16][CH3:17]>C(#N)C>[CH3:13][P:14]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[N+:10]([O-:12])=[O:11])(=[O:18])[O:15][CH2:16][CH3:17]

参加物

4

反応物 2

HCID 107071,2-DinitrobenzeneHCID 85063Diethyl methylphosphonite

生成物 1

HCID 13292704HCID 13292704、化合物

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

A mixture of 1,2-dinitrobenzene (2.48 mmol), diethyl methylphosphonite (3.72 mmol) and acetonitrile (3 ml) is stirred at RT overnight. The reaction is concentrated to dryness, and the residue is purified by preparative thin layer chromatography (TLC) to yield ethyl P-methyl-2-nitrophenyl-phosphinate.

後処理

  1. concentrationThe reaction is concentrated to dryness
  2. customthe residue is purified by preparative thin layer chromatography (TLC)

出典と根拠

ORDレコード
ord-c34ce62fdba4431e8122437a12d3da68
出典データセット
uspto-grants-1985_05
特許番号
US04520197

関連ノート

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