Methyl iodide → HCID 20265013、化合物

HRID 463690ノート

反応式

HRID 463690 の反応式
[N+:1]([C:4]1[C:17]2[C:16](=[O:18])[C:15]3[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=3)[NH:9][C:8]=2[CH:7]=[CH:6][CH:5]=1)([O-:3])=[O:2].[H-].[Na+].[CH3:21]I>CN(C)C=O>[CH3:21][N:9]1[C:10]2[C:15](=[CH:14][CH:13]=[CH:12][CH:11]=2)[C:16](=[O:18])[C:17]2[C:4]([N+:1]([O-:3])=[O:2])=[CH:5][CH:6]=[CH:7][C:8]1=2

参加物

5

反応物 3

HCID 6328Methyl iodideHCID 24758Sodium hydrideHCID 988489(10H)-Acridinone, 1-nitro-

生成物 1

HCID 20265013HCID 20265013、化合物

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

4.8 g of 1-nitro-9-acridanone are dissolved in 200 ml of dimethylformamide and treated with 0.5 g of sodium hydride. The deep red solution is treated with 2.5 ml of methyl iodide and stirred at room temperature for 4 hours. The yellow precipitate obtained is filtered and washed successively with dimethylformamide, water, ethanol and ether. There is obtained 10-methyl-1-nitro-9-acridanone of melting point 308°-309°.

後処理

  1. customThe yellow precipitate obtained
  2. filtrationis filtered
  3. washwashed successively with dimethylformamide, water, ethanol and ether

出典と根拠

ORDレコード
ord-f447da1f560c46aaa2e9b4783110f236
出典データセット
uspto-grants-1985_10
特許番号
US04544659

反応ノート

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