1-Octene → Gamma-Decalactone

HRID 46745

反応式

HRID 46745 の反応式
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[C:9]([O-:12])(=[O:11])[CH3:10].[K+]>C(O)(=O)C>[CH2:6]([CH:7]1[O:12][C:9](=[O:11])[CH2:10][CH2:8]1)[CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

参加物

4

反応物 2

HCID 81251-OcteneHCID 517044Potassium Acetate

生成物 1

HCID 12813Gamma-Decalactone収率 61%

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

Octene-1 in an amount of 2.24 g. and 5.1 g. of Mn2O3 (comprising two equivalents of Mn+3 based on titration value) were refluxed under nitrogen in 200 ml. glacial acetic acid containing 60 g. potassium acetate. After a period of less than two hours, gamma-n-hexyl-butyrolactone was obtained in a yield of 61%.

後処理

  1. waitAfter a period of less than two hours

出典と根拠

ORDレコード
ord-43204c96c25d493ba43892f30698f076
出典データセット
uspto-grants-1979_11
特許番号
US04175089

関連ノート

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