Platinous chloride → HCID 178435846、化合物

HRID 476542

反応式

HRID 476542 の反応式
[Br:1][C:2]1[C:3]2[N:7]([CH2:8][CH3:9])[C:6]([CH:10]=[C:11]3[N:37]=[C:14]([CH:15]=[C:16]4[NH:32][C:19](=[C:20]([CH2:30][CH3:31])[C:21]5[C:22]([CH2:28][CH3:29])=[C:23]([CH2:26][CH3:27])[C:24]=1[N:25]=5)[C:18]([CH2:33][CH3:34])=[C:17]4[CH2:35][CH3:36])[CH:13]=[CH:12]3)=[C:5]([CH2:38][CH3:39])[C:4]=2[CH2:40][CH3:41].[Pt:42](Cl)Cl>CN(C)C=O>[Br:1][C:2]1[C:3]2[N:7]([CH2:8][CH3:9])[C:6]([CH:10]=[C:11]3[N:37]=[C:14]([CH:15]=[C:16]4[NH:32][C:19](=[C:20]([CH2:30][CH3:31])[C:21]5[C:22]([CH2:28][CH3:29])=[C:23]([CH2:26][CH3:27])[C:24]=1[N:25]=5)[C:18]([CH2:33][CH3:34])=[C:17]4[CH2:35][CH3:36])[CH:13]=[CH:12]3)=[C:5]([CH2:38][CH3:39])[C:4]=2[CH2:40][CH3:41].[Pt:42]

参加物

4

反応物 2

HCID 2770Platinous chlorideHCID 178435845HCID 178435845、化合物

生成物 1

HCID 178435846HCID 178435846、化合物

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

In a suitable 150 ml vessel 50 ml of dimethylformamide is brought to reflux and 20 mg 5-bromo octaethylporphine free base is added and dissolved. To this solution 8 mg platinum chloride is added and permitted to react for about 20 minutes. Thereafter, the reaction mixture is permitted to cool and crystal formation promoted by the addition of 50 ml distilled water. The reaction mixture is allowed to sit for about twenty four hours to increase crystal size. The reaction mixture is filtered by vacuum filtration and the solids retained.

後処理

  1. temperatureto reflux
  2. dissolutiondissolved
  3. customto react for about 20 minutes
  4. temperatureto cool
  5. additioncrystal formation promoted by the addition of 50 ml
  6. distillationdistilled water
  7. waitto sit for about twenty four hours
  8. temperatureto increase crystal size
  9. filtrationThe reaction mixture is filtered by vacuum filtration

出典と根拠

ORDレコード
ord-f01890c04f3b4fe4939f16b4f5a0396c
出典データセット
uspto-grants-1989_12
特許番号
US04885114

関連ノート

読み込み中…