4-Toluenesulfonyl chloride → HCID 13957272、化合物

HRID 485299

反応式

HRID 485299 の反応式
[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7](Cl)(=[O:9])=[O:8])=[CH:3][CH:2]=1.[Cl:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][OH:21]>N1C=CC=CC=1>[C:1]1([CH3:11])[CH:6]=[CH:5][C:4]([S:7]([O:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][Cl:12])(=[O:9])=[O:8])=[CH:3][CH:2]=1

参加物

4

反応物 2

HCID 73974-Toluenesulfonyl chlorideHCID 900121-Octanol, 8-chloro-

生成物 1

HCID 13957272HCID 13957272、化合物

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

p-Toluenesulphonyl chloride (20.5 g) was added to a mixture of 8-chloro-1-octanol (17.7 g) and pyridine (50 ml) of 0°. After a hour the solution was added to ice and the mixture was extracted with ether. The ethereal solution was washed with dilute hydrochloric acid, dried with magnesium sulfate, and evaporated to yield the title compound as an oil.

後処理

  1. additionAfter a hour the solution was added to ice
  2. extractionthe mixture was extracted with ether
  3. washThe ethereal solution was washed with dilute hydrochloric acid
  4. dry with materialdried with magnesium sulfate
  5. customevaporated

出典と根拠

ORDレコード
ord-b240b72b7cec4533bb47620064d06262
出典データセット
uspto-grants-1985_08
特許番号
US04536503

関連ノート

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