Pyridine → 1-(2-Ethoxy-2-oxoethyl)pyridin-1-ium chloride

HRID 487342ノート

反応式

HRID 487342 の反応式
[N:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl:7][CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10]>C(OCC)(=O)C>[Cl-:7].[CH2:12]([O:11][C:9]([CH2:8][N+:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)=[O:10])[CH3:13]

参加物

4

反応物 2

HCID 1049PyridineHCID 7751Ethyl chloroacetate

生成物 1

HCID 111381401-(2-Ethoxy-2-oxoethyl)pyridin-1-ium chloride

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒

実験手順

Pyridine (1 equivalent) and ethyl chloroacetate (1 equivalent) in ethyl acetate were heated (70° C.) for 24 hours. The reaction mixture was cooled to room temperature and the resulting crystalline pyridinium salt filtered, washed with ethyl acetate, and dried in vacuum.

後処理

  1. filtrationthe resulting crystalline pyridinium salt filtered
  2. washwashed with ethyl acetate
  3. customdried in vacuum

出典と根拠

ORDレコード
ord-b15aed9988544fb3aa12a2a2f218286b
出典データセット
uspto-grants-1994_03
特許番号
US05294721

反応ノート

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