Sulfuric Acid → Octyl acrylate

HRID 513883

反応式

HRID 513883 の反応式
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:9]([OH:13])(=[O:12])[CH:10]=[CH2:11].S(=O)(=O)(O)O>>[C:9]([O:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])(=[O:12])[CH:10]=[CH2:11]

参加物

4

反応物 3

HCID 1118Sulfuric AcidHCID 6581Acrylic AcidHCID 81251-Octene

生成物 1

HCID 17258Octyl acrylate

実験手順

To 1.00 g (0.00891 mole, 1 eq) of 1-octene heated to 50° C. was added a solution of 0.706 g (0.00980 mole, 1.1 eq) of acrylic acid and 2.00 g of a 96 wt-% solution of sulfuric acid (18 M, 0.0196 mole, 2.2 eq). After 15 minutes at 70° C. all the olefin was consumed but only 30% of the product was the desired acrylate.

後処理

  1. customAfter 15 minutes at 70° C. all the olefin was consumed

出典と根拠

ORDレコード
ord-12243f2f6dd04e45a83cbcd11720b0b6
出典データセット
uspto-grants-2015_08
特許番号
US09102774B2

関連ノート

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