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Hydrochloric Acid → Pyridinium Trifluoromethanesulfonate

HRID 537710
ノート
印刷プレビュー

反応式

HRID 537710 の反応式
C1([Si](OC)(OC)OC)C=CC=CC=1.C(O[Si](OCC)(OCC)OCC)C.C[Si](OCC)(OCC)OCC.[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].CO[Si](CC[C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][N+:56]=1C)(OC)OC.Cl.C(OCC(O)C)C>O.CC(C)=O.CO.C(O)C>[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].[NH+:56]1[CH:57]=[CH:58][CH:59]=[CH:60][CH:55]=1
参加物実験手順後処理出典と根拠反応ノート

参加物

11

反応物 6

HCID 313Hydrochloric Acid2 回HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 86654379HCID 86654379、化合物

生成物 1

HCID 2734866
Pyridinium Trifluoromethanesulfonate

試薬・触媒・溶媒 4

HCID 180Acetone溶媒2 回HCID 702Ethanol溶媒HCID 887Methanol溶媒2 回HCID 962Water溶媒

実験手順

4.92 g of phenyltrimethoxysilane, 72.39 g of tetraethoxysilane, 22.04 g of methyltriethoxysilane, 0.56 g of the 30% methanol solution of trimethoxysilylethylmethylpyridinium trifluoromethanesulfonate, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.13 g of 0.01 M hydrochloric acid was added to the mixed solution. The mixed solution was subjected to the reaction for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol and methanol as reaction by-products, acetone, water, and hydrochloric acid were distilled off under reduced pressure to obtain a hydrolysis-condensation product. The polymer thus obtained corresponded to Formula (VII-22):

後処理

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customThe mixed solution was subjected to the reaction for 240 minutes
  6. customthe resultant reaction solution
  7. distillationwere distilled off under reduced pressure
  8. customto obtain a hydrolysis-condensation product
  9. customThe polymer thus obtained

出典と根拠

ORDレコード
ord-76385a962aed4d7eaccb2f4f3d9bebaa
出典データセット
uspto-grants-2014_10
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08864894B2

反応ノート

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