2-Propenoic acid, 3-hydroxypropyl ester → Isopropenylphosphonic Acid Hydroxypropylacrylate

HRID 543454

反応式

HRID 543454 の反応式
[C:1]([P:4](=[O:7])([OH:6])[OH:5])([CH3:3])=[CH2:2].[OH:8][CH2:9][CH2:10][CH2:11][O:12][C:13](=[O:16])[CH:14]=[CH2:15].S(OOS([O-])(=O)=O)([O-])(=O)=O.[NH4+].[NH4+].S(OOS([O-])(=O)=O)([O-])(=O)=O>O>[C:1]([P:4](=[O:5])([OH:7])[OH:6])([CH3:3])=[CH2:2].[OH:8][CH2:9][CH2:10][CH2:11][O:12][C:13](=[O:16])[CH:14]=[CH2:15]

参加物

6

反応物 4

HCID 331012-Propenoic acid, 3-hydroxypropyl esterHCID 62648Ammonium PersulfateHCID 107879PeroxydisulfateHCID 557541Isopropenylphosphonic acid

生成物 1

HCID 86739384Isopropenylphosphonic Acid Hydroxypropylacrylate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Using the apparatus and methodology as described in Example 1, isopropenyl phosphonic acid (61.6 g, 54%, 0.27 mole), hydroxypropylacrylate (16.6 g, 0.13 mole) and water (121.8 g) were charged in the reactor. Ammonium persulfate (6 g) was added. After 11/2 hours of reflux, 6 g additional persulfate was added followed by an equivalent reflux period. The final pH of the yellow solution was 0.72.

後処理

  1. additionwere charged in the reactor
  2. temperatureAfter 11/2 hours of reflux
  3. temperaturean equivalent reflux period

出典と根拠

ORDレコード
ord-5d4d50ba7f4644d680f84acc41bdccb2
出典データセット
uspto-grants-1984_05
特許番号
US04446028

関連ノート

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