Diethyl Ether → HCID 67199887、化合物
反応式
[CH3:1][N:2]([CH3:15])[C:3]1[CH:8]=[CH:7][C:6]([C:9]2[CH:14]=[CH:13][N:12]=[CH:11][CH:10]=2)=[CH:5][CH:4]=1.[CH2:16]([I:18])[CH3:17].C(OCC)C>C(#N)C>[I-:18].[CH3:1][N:2]([CH3:15])[C:3]1[CH:4]=[CH:5][C:6]([C:9]2[CH:10]=[CH:11][N+:12]([CH2:16][CH3:17])=[CH:13][CH:14]=2)=[CH:7][CH:8]=1参加物
5
実験手順
IDT321. Was prepared by refluxing N,N-dimethyl-4-(pyridine-4-yl) aniline (II) in acetonitrile in the presence of ethyl iodide. Upon cooling diethyl ether was added and the product crystallized resulting in a 18% yield of 4-(4-(dimethylamino)phenyl)-1-ethylpyridinium iodide (IDT321) (IV).
後処理
- customWas prepared
- additionwas added
- customthe product crystallized
出典と根拠
- ORDレコード
- ord-8ac69fa2f8b74e39863302a8ef815c00
- 出典データセット
- uspto-grants-2011_05
- 特許番号
- US07947255B2
反応ノート
読み込み中…