HCID 689895、化合物 → tert-Butyl 2-benzylhydrazinecarboxylate

HRID 582416ノート

反応式

HRID 582416 の反応式
[C:1]([O:5][C:6]([NH:8][N:9]=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)=[O:7])([CH3:4])([CH3:3])[CH3:2].[H][H]>O1CCCC1.[Pd]>[C:1]([O:5][C:6]([NH:8][NH:9][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)=[O:7])([CH3:4])([CH3:2])[CH3:3]

参加物

5

反応物 2

HCID 689895HCID 689895、化合物HCID 178418361HCID 178418361、化合物

生成物 1

HCID 10656659tert-Butyl 2-benzylhydrazinecarboxylate収率 96.2%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 8028Tetrahydrofuran溶媒

実験手順

##STR185## To a solution of N'-benzylidenehydrazinecarboxylic acid tert-butyl ester (2.7 g, 12.3 mmol) in tetrahydrofuran (100 ml) was added 10% palladium on carbon (0.3 g) and the mixture was hydrogenated with 280 ml of hydrogen for 40 min at atmospheric pressure. The mixture was filtered through a plug of celite and the filtrate was concentrated in vacuo to give 2.63 g of N'-benzylhydrazinecarboxylic acid tert-butyl ester.

後処理

  1. filtrationThe mixture was filtered through a plug of celite
  2. concentrationthe filtrate was concentrated in vacuo

出典と根拠

ORDレコード
ord-7885615e5266416ba13cfce617241f7e
出典データセット
uspto-grants-1999_07
特許番号
US05922770

反応ノート

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