Pentafluoroaniline → 501670-16-2

HRID 601095

反応式

HRID 601095 の反応式
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([CH:15]=NC2C(Br)=CC=CC=2Br)[C:6]=1[OH:25])([CH3:4])([CH3:3])[CH3:2].[F:26][C:27]1[C:33]([F:34])=[C:32]([F:35])[C:31]([F:36])=[C:30]([F:37])[C:28]=1[NH2:29].C(C1C(O)=C(C=C(C(C)(C)C)C=1)C=O)(C)(C)C>>[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([CH:15]=[N:29][C:28]2[C:27]([F:26])=[C:33]([F:34])[C:32]([F:35])=[C:31]([F:36])[C:30]=2[F:37])[C:6]=1[OH:25])([CH3:4])([CH3:3])[CH3:2]

参加物

4

反応物 3

HCID 13040PentafluoroanilineHCID 6880233,5-Di-tert-butylsalicylaldehydeHCID 136346710HCID 136346710、化合物

生成物 1

HCID 135509894501670-16-2

実験手順

Employing an analogous procedure to that described above for the synthesis of 2,4-bis(tert-butyl)-6-[[(2,6-dibromophenyl)imino]methyl]phenol, 2,3,4,5,6-pentafluoroaniline (0.54 g, 2.9 mmol) was added to 3,5-di-tert-butyl-2-hydroxybenzaldehyde (0.70 g, 2.9 mmol). The product was purified by recrystallisation from hot MeOH and isolated as yellow crystals.

後処理

  1. customThe product was purified by recrystallisation from hot MeOH
  2. customisolated as yellow crystals

出典と根拠

ORDレコード
ord-1224c7f7869c44258aeb252783b2e5e7
出典データセット
uspto-grants-2011_03
特許番号
US07902308B2

関連ノート

読み込み中…