反応式
COc1ccc(Cl)cc1.Cc1cc(C)c(B(O)O)c(C)c1>C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.C1COCCO1.CCCCCCCCP(CCCCCCCC)CCCCCCCC.O.O=P([O-])([O-])[O-].[K+].[K+].[K+].[Ni]>COc1ccc(-c2c(C)cc(C)cc2C)cc1参加物
8
反応条件
- 温度
- 60 °C
実験手順
pre-ligate Ni(cod)2 and phosphine ligand in dioxane for 15 minutes in a separate plate
後処理
- additionDilute with acetonitrile
- aliquot手順は記録されていません
- customDiluent solution was made in 1 L batches with 950 mL acetonitrile, 25 mL water, 25 mL glacial acetic acid, and 53 mg 4,4’-di-tert-butylbiphenyl as an external standard (0.2 equiv standard per reaction). Aliquot taken from each well (47 ul) is added into 753 ul of diluent solution
出典と根拠
- ORDレコード
- ord-09d62334403d4df0adcb2e79f2f2be86
- 出典データセット
- Ni-catalyzed Suzuki Miyaura cross-coupling
- 元リンク
- 出典を表示
関連ノート
読み込み中…