3-Nitrobenzanilide → 3-Aminobenzanilide
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:16]=[CH:17][CH:18]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:8])([O-])=O>[Pd].C(O)C>[NH2:1][C:4]1[CH:5]=[C:6]([CH:16]=[CH:17][CH:18]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:8]参加物
4
実験手順
10% Palladium on carbon (2.0 g) was added to a solution of 3-nitro-N-phenyl-benzamide (20 g, 83 mmol) in ethanol (225 mL) and the mixture was hydrogenated at 45 psi for 2 hours. The mixture was filtered through diatomaceous earth and concentrated to give a colorless solid (mp 118-120° C., 16 g, 90%).
後処理
- filtrationThe mixture was filtered through diatomaceous earth
- concentrationconcentrated
出典と根拠
- ORDレコード
- ord-0de9ee7ba0624e6f89c88e7033107b63
- 出典データセット
- uspto-grants-1999_12
- 特許番号
- US05998463
反応ノート
読み込み中…