Glyceraldehyde → 4-(n-Hexadecylamino)benzoyl glyceraldehyde

HRID 615063

反応式

HRID 615063 の反応式
[O:1]=[CH:2][CH:3]([CH2:5][OH:6])[OH:4].Cl.[CH2:8]([NH:24][C:25]1[CH:33]=[CH:32][C:28]([C:29](Cl)=[O:30])=[CH:27][CH:26]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23].C(Cl)(Cl)Cl>CN(C)C1C=CN=CC=1.O>[CH2:8]([NH:24][C:25]1[CH:33]=[CH:32][C:28]([C:29]([C:2]([CH:3]([CH2:5][OH:6])[OH:4])=[O:1])=[O:30])=[CH:27][CH:26]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]

参加物

6

反応物 3

HCID 751GlyceraldehydeHCID 6212ChloroformHCID 132553224-Hexadecylaminobenzoyl chloride hydrochloride

生成物 1

HCID 213269534-(n-Hexadecylamino)benzoyl glyceraldehyde

試薬・触媒・溶媒 2

HCID 142844-(Dimethylamino)pyridine触媒HCID 962Water溶媒

実験手順

To a mixture of 3.6 g. of glyceraldehyde and 2.44 g. of 4-dimethylaminopyridine in an ice-bath is added 4.16 g. of 4-(n-hexadecylamino)benzoyl chloride hydrochloride. After 4 hours at room temperature, chloroform and water are added. The chloroform extract is chromatographed quickly and evaporated in vacuo to yield 4-(n-hexadecylamino)benzoyl glyceraldehyde.

後処理

  1. additionTo a mixture of 3.6 g
  2. extractionThe chloroform extract
  3. customis chromatographed quickly
  4. customevaporated in vacuo

出典と根拠

ORDレコード
ord-66fef1a1db6948c9940bcde96e59a27b
出典データセット
uspto-grants-1979_03
特許番号
US04146546

関連ノート

読み込み中…