m-Chloroperbenzoic acid → HCID 178504633、化合物
反応式
[NH2:1][C:2]1[NH:3][S:4](=[O:13])(=[O:12])[N:5]=[C:6]([CH2:8][CH2:9][S:10][CH3:11])[N:7]=1.ClC1C=CC=C(C(OO)=[O:22])C=1>CO.C(Cl)(Cl)Cl>[NH2:1][C:2]1[NH:3][S:4](=[O:13])(=[O:12])[N:5]=[C:6]([CH2:8][CH2:9][S:10]([CH3:11])=[O:22])[N:7]=1参加物
5
実験手順
To a solution of 3-amino-5-[2-(methylthio)ethyl]-1,2,4,6-thiatriazine-1,1-dioxide (1.22 gm, 5.5 mmol) in warm methanol (20 ml) there was added dropwise a solution of 80% pure m-chloroperbenzoic acid (1.2 gm, 5.6 mmol) in chloroform (20 ml). The product crystallized from solution during the addition and was collected by filtration and washed with diethyl ether to give 1.27 gm of pure product, m.p. 180°-182° C.
後処理
- customThe product crystallized from solution during the addition
- filtrationwas collected by filtration
- washwashed with diethyl ether
出典と根拠
- ORDレコード
- ord-bf78132cdaa44872836e427e004f87b4
- 出典データセット
- uspto-grants-1985_02
- 特許番号
- US04497810
反応ノート
読み込み中…