Sodium Hydroxide → 2,5-Dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane

HRID 616641

反応式

HRID 616641 の反応式
[OH-:1].[Na+].[CH2:3]([CH:5]([CH2:9][CH2:10][CH2:11][CH3:12])[C:6](Cl)=[O:7])[CH3:4].[CH3:13][C:14]([O:23][OH:24])([CH2:16][CH2:17][C:18]([CH3:22])([O:20][OH:21])[CH3:19])[CH3:15]>>[CH3:15][C:14]([O:23][O:24][C:6](=[O:1])[CH:5]([CH2:3][CH3:4])[CH2:9][CH2:10][CH2:11][CH3:12])([CH2:16][CH2:17][C:18]([CH3:22])([O:20][O:21][C:6](=[O:7])[CH:5]([CH2:3][CH3:4])[CH2:9][CH2:10][CH2:11][CH3:12])[CH3:19])[CH3:13]

参加物

4

反応物 3

HCID 14798Sodium HydroxideHCID 791032-Ethylhexanoyl chlorideHCID 5204702,5-Dimethylhexane 2,5-dihydroperoxide

生成物 1

HCID 1144482,5-Dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane

反応条件

温度
30 °C

実験手順

Sodium hydroxide (25% aqueous solution), 2-ethylhexanoyl chloride (93%), 2,5-dimethyl-2,5-dihydroperoxyhexane (70%) are introduced into the mixing reactor (21) along with an aliphatic organic solvent (hexane, heptane etc.) at the rate of 51 lbs/hr, 31 lbs/hr and 38 lbs/hr respectively. The temperature in the reaction zone 21 is maintained at about 30° C and that in the after reaction zone 22 at about 20° C. The product 2,5-dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane is obtained at the rate of about 50 lbs/hr.

後処理

  1. customthat in the after reaction zone 22 at about 20° C

出典と根拠

ORDレコード
ord-6ebc1d152e3f490aa29dc68de9327810
出典データセット
uspto-grants-1978_02
特許番号
US04075236

関連ノート

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