Water → Acetophenone

HRID 621830

反応式

HRID 621830 の反応式
[C:1]1([CH:7]([CH3:9])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(C1C=CC(C(C)C)=CC=1)(C)C.[CH3:22][C:23](C)([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[OH:24].[OH2:32]>>[C:23]([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)(=[O:24])[CH3:22].[O-:32][OH:24].[C:1]1([CH:7]([CH3:9])[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

6

反応物 4

HCID 962WaterHCID 7406Cumene2 回HCID 74861,4-DiisopropylbenzeneHCID 120532-Phenyl-2-propanol

生成物 2

HCID 7410AcetophenoneHCID 53627471Cumen hydroperoxide

実験手順

Using 79.9 g (0.665 mole) of cumene in lieu of p-diisopropylbenzene, oxidation was carried out in the same apparatus and under the same conditions as those employed in Example 1. The reaction product obtained subsequent to its water washing and drying was an oily matter whose weight was 79.6 g. According to results of a high-performance liquid chromatographic analysis, the oily matter was found to contain 3.1 g (0.026 mole; conversion: 96.1%) of cumene and 75.3 g (0.553 mole; yield: 83.2 mole %) of dimethylphenylcarbinol. Acetophenone or cumene hydroperoxide was not formed practically.

後処理

  1. customdrying
  2. customto results of a high-performance liquid chromatographic analysis

出典と根拠

ORDレコード
ord-2fb7bffb1d064be3b513c787f38a15b1
出典データセット
uspto-grants-1989_04
特許番号
US04825007

関連ノート

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