反応式
[C:1]([O:4][C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][CH:13]=1)[C:8](Cl)=[O:9])(=[O:3])[CH3:2].[K].[CH3:15][S:16]([CH3:19])(=[NH:18])=[O:17]>O1CCCC1>[C:1]([O:4][C:5]1[CH:6]=[C:7]([CH:11]=[CH:12][CH:13]=1)[C:8]([N:18]=[S:16]([CH3:19])([CH3:15])=[O:17])=[O:9])(=[O:3])[CH3:2]参加物
4
反応条件
- 温度
- -35 °C
実験手順
A solution of 99.3 g of m-acetoxybenzoyl chloride in 150 ml of absolute tetrahydrofuran is added dropwise at -35° C. during 20 minutes while stirring to the dimethyl sulphoximine potassium salt suspension and the mixture is then stirred at -35° C. for 30 minutes. N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine is thus formed in suspension.
出典と根拠
- ORDレコード
- ord-7abe3c7ad9e0455ab3840a266774c0b4
- 出典データセット
- uspto-grants-1985_12
- 特許番号
- US04556413
関連ノート
読み込み中…