N-bromobutanimide → 2-(2,2-Dichlorovinyl)-benzyl bromide

HRID 64916

反応式

HRID 64916 の反応式
[Cl:1][C:2]([Cl:11])=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH3:10].[Br:12]N1C(=O)CCC1=O>ClC(Cl)(Cl)C>[Cl:1][C:2]([Cl:11])=[CH:3][C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[CH2:10][Br:12]

参加物

4

反応物 2

HCID 67184N-bromobutanimideHCID 137131272-(2,2-Dichlorovinyl)-toluene

生成物 1

HCID 137131282-(2,2-Dichlorovinyl)-benzyl bromide

試薬・触媒・溶媒 1

HCID 62781,1,1-Trichloroethane溶媒

実験手順

211 g (1.13 moles) of 2-(2,2-dichlorovinyl)-toluene, 251 g (1.41 moles) of N-bromosuccinimide and 2 g of azoisobutyronitrile in 1300 ml of dry 1,1,1-trichloroethane are refluxed, an additional 1 g of azoisobutyronitrile is added to the reaction mixture after one hour, and heating is continued for a further hour.

後処理

  1. temperatureheating
  2. waitis continued for a further hour

出典と根拠

ORDレコード
ord-760ebf0ea2264cd3a5e2e56550388425
出典データセット
uspto-grants-1986_09
特許番号
US04611010

関連ノート

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